Hydrogen sulphide stress corrosion cracking in materials for. Element sulfide stress cracking ssc testing according the nace tm0177 iso 15156 standards help ensure sour service pipelines reliability and longevity. Sulfide stress cracking mostly occurs in very highly acidic environments. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Tt, on sulfide stress cracking ssc behaviors was estimated mainly via double cantilever beam dcb and electrochemical hydrogen permeation ehp tests. Sulfide stress crackingresistant drill pipe addresses h2s. All different forms of corrosion are explained by nace certified corrosion. Hydrogen sulfide cracking of carbon and alloy steels. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Sulfide stress cracking of nickelcontaining lowalloy. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. In this chapter the terms eac and scc are generally interchangeable. Ssc is a form of spontaneous brittle breakdown in occurring in highstrength. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism.
Images are produced from the best available original document. Sulfide stress cracking oil and gas pipelines wiley online library. The list of acronyms and abbreviations related to ssc sulfide stress cracking. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials when the environment contains wet h 2 s. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body. Brittle failure b cracking under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. The need for more adequate engineering data and a better theoretical understanding of sulfide cracking has led to a more thorough study of several variables involved in the sulfide cracking of carbon steel.
The national association of corrosion engineers nace test method tm0177 is widely used to qualify metals for resistance to sulfide stress cracking and stress. Effect of ph and h 2 s concentration on sulfide stress. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. Sulfide stress cracking nace mr01752002, mr0175iso 15156. The critical stress intensity factor for sulfide stress cracking, kissc, k issc of fully martensitic microstructures tempered to strength levels in the 620 to 725mpa range were 56 and 40mpam 12, whereas fully tempered bainitic microstructures with similar ys gave k issc values between 42 and 32mpam 12 garber, 1983. Element performs sulfide stress cracking ssc testing of metals subject to cracking under the combined action of tensile stress and corrosion in the presence of water and h2s, in compliance with nace tm0177 iso 15156 standards. Sulfide stress cracking ssc testing southwest research institute. Detection of sulfide stress cracking in a supermartensitic stainless.
Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Two point bent beam, nace tensile, cring and dcb stress. The role of ph value and h2s concentration on the sulfide stress corrosion cracking of api 2205 duplex stainless steel was studied by means of slow strainrate tests, polarization curve. Sulfide stress cracking an overview sciencedirect topics. Sulfide stress crackingresistant drill pipe addresses h2s challenges. Pdf sulfide stress corrosion cracking and hydrogen. Summary sulfide stress cracking ssc is just one of several forms of hydrogen. Hardness, yield strength, stress and microstructure were the primary metallurgical variables studied. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Materials free fulltext sulfide stress cracking behavior of a.